1.
Richard James (2003) by Richard James
2.
Cuir d'Oranger (2005) by Miller Harris
3.
Cuba (2002) by Czech & Speake
4.
Iskander (2006) by Parfum d'Empire
No.5 is tricky as I have not tried
Tiberius (2009) by Star Trek ( Alas!
Mojo by Austin Powers came out in 1999) nor
Vetiver by Givenchy which is a 1959 scent but it was discontinued and reintroduced in 2007. Would that count? Also keep in mind that the new millennium, as long as we're going to be accurate, did NOT begin in 2000 but on 1/1/2001-- I knew you really wanted to know that

Nor Creed's
Feuille Verte (2006)--um spotted at Marshall's, anyone??
For crying out loud! I haven't even had a whiff of:
Calum (2006) by Calum Best
Encre Noire (2006) by Lalique
Rainforest or Rebellius by Ayala Moriel
Tabacco (2008) by Odori
Tuscan Soul (2008) by Salvatore Ferragamo
No wonder I'm falling apart!
Mario