A place that I would HIGHLY recommend is called Jacob & Sebastian-622 Queen St West, Toronto (they have been around for 2 and a half years and are opening a second spot this November in the Distillery District). They are mostly about niche-market skin care, shaving and body products, but they definitely had a LOT of amazing scents. They carry Santa Maria Novella, CB I hate perfume, Boudicca, Compagnie de Provence and some lines I have not heard of such as "Portland General Store" (organic colognes that smell of tobacco, wood, whiskey etc...). Also, the gentleman working there mentioned they were bringing in L'Artisan. Hope that helps.
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Thanks for the list! I would like to add Jacob & Sebastian at Queen and Bathurst. They are mostly about niche-market bath, body and skin care but had a great selection of Santa Maria Novella, I hate Perfume, and Boudicca. Also,the guy working said they were adding L'Artisan and Eau D'Italie to the roster this Dec. Cheers!