Interesting idea. Deciding what to profile would be a challenge, unless we employ a sort of random-number-generator selection method.
What if we cast a little broader net and chose a class, such as Chypre, and name 10 possible scents from that class members could sample, which would give each person a little freedom of choice. Of course, the more ambitious amongst us, or those who have access to more frags, could test all 10. But, more than likely, almost everyone could test at least one from each class.
What about a monthly theme? January=Orientals, February=Animalics, March=Chypres, April=Florals, etc. Then we could plan ahead.
Just stuff off the top of my head. Love your ambitious creativity!