I have gotten free samples (2) by phoning the SA at Saks whom I had spoken to personally before; I have not ordered online but the website states:
Can I get free samples?
While free samples are only given out with online orders, Bond No. 9 does have a sampling program that we invite all of our valued customers to participate in. You can log on to www.bondno9.com and order 6 samples for $15 or call our toll free number at 1.877.276.3369 and speak to a trained sales representative. This minimum charge covers our shipping and handling fee and gives you the opportunity to try our fragrances before you make a purchase.