from your list, adventure, black xs and 212 men are the standouts to me. everyone your age has either le male or joop homme.
for your trip to spain, will you not be able to save some cash to hit up duty free? you can check which brands are stocked in the airport/terminal you fly from, and do some research and sampling beforehand- sometimes you can get good deals in the airport.
you say those are all the scents you want this year, but dont forget there will be a bunch of new releases around april and september. travelling in march, you might see them before they are in stores.