You have a very nice wardrobe! But, it's full of heavy hitters, not much "light and fresh" in there that could ease someone into perfumery
From your wardrobe, what about Dzing? it's abstract, interesting, but maybe too strange for her. Worth a try though. I would try variations of Shalimar, the old Legere and the new Initial, both are subtly gourmand and non-floral. And there is always Bulgari Black.