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Blanche Dubois is not a TV character (that I know of) but it was such a good match that who cares? Here's another (and I am dating myself!):

Jimmy Sparks-Kanebo's Eroica

Samantha Stewart - Tweed by Lentheric

Christopher Foyle - Trumper's Eau de Quinine

Shawn Spencer--Aventus

The Fonz wearing No 5! I love this against type thing.

Steve Austin--Andron (okay, it was a few years late)
Maddie Hayes--Ivoire de Balmain
David Addison--Andron
Jennifer Hart--First by VCA
Jonathan Hart--Andron.....no, seriously probably Aramis or...